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Evaluation of a technique for determining Re and PGEs in geological samples by ICP-MS coupled with a modified Carius tube digestion
LIANG QI;  MEI-FU ZHOU;  CHRISTINA YAN WANG;  MIN SUN
2007
Source PublicationGeochemical Journal
Volume41Issue:6Pages:407-414
Abstract

In the determination of Re and platinum group elements in geological samples, various techniques have been employed for digesting samples, including Carius tube, high-pressure asher (HPA-S), alkali fusion and nickel sulfide fire assay. The normal Carius tube technique is able to digest relatively small amount of sample and has a possible safety problem caused by a high internal pressure. This paper reports a modified Carius tube method which utilizes a sealed stainless steel high-pressure autoclave filled with water to prevent explosion of the tube. During heating, the external and internal pressures of the Carius tube increase simultaneously, such that the possible explosion of Carius tube can be avoided. Consequently, this technique allows a higher temperature (up to 330°C), a greater volume of aqua regia (up to 2/3 of the total volume of the Carius tube) and thus larger sample mass (12 g) relative to the normal Carius tube technique. Fairly good agreement were obtained for PGE poor mafic rocks (IPGE < 0.03 ng/g). The efficiency to dissolve ultramafic rocks and chromites at different temperatures was investigated. We demonstrate that this technique is more effective than normal Carius tube technique for ultramafic rocks and chromites containing refractory minerals and the detection limits and precision can be improved for PGE poor mafic samples. The total procedural blanks are lower than 0.003 ng for Os, 0.03 ng for Re, Ir, Ru and Rh and 0.4 ng for Pd and Pt.

KeywordRhenium Pges Icp-ms Carius Tube High Pressure Autoclave
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.gyig.ac.cn/handle/42920512-1/8110
Collection矿床地球化学国家重点实验室
Affiliation1.Department of Earth Sciences, The University of Hong Kong, Pokfulam Road, Hong Kong, SAR, China
2.State Key Lab. of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China
Recommended Citation
GB/T 7714
LIANG QI;MEI-FU ZHOU;CHRISTINA YAN WANG;MIN SUN. Evaluation of a technique for determining Re and PGEs in geological samples by ICP-MS coupled with a modified Carius tube digestion[J]. Geochemical Journal,2007,41(6):407-414.
APA LIANG QI;MEI-FU ZHOU;CHRISTINA YAN WANG;MIN SUN.(2007).Evaluation of a technique for determining Re and PGEs in geological samples by ICP-MS coupled with a modified Carius tube digestion.Geochemical Journal,41(6),407-414.
MLA LIANG QI;MEI-FU ZHOU;CHRISTINA YAN WANG;MIN SUN."Evaluation of a technique for determining Re and PGEs in geological samples by ICP-MS coupled with a modified Carius tube digestion".Geochemical Journal 41.6(2007):407-414.
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