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Compressibility of pyrochlore-type MgZrSi2O7 determined by in situ X-ray diffraction in a large-volume high pressure apparatus
Shuangmeng Zhai;  Shuangming Shan;  Daisuke Yamazaki;  Ken-ichi Funakoshi
2013
发表期刊High Pressure Research
卷号33期号:1页码:1-7
摘要

The pyrochlore-type MgZrSi2O7 has been investigated by in situ synchrotron energy-dispersive X-ray diffraction measurements up 24.3 GPa at room temperature in a multianvil high pressure apparatus. The pressure has been calculated using an internal gold metal pressure calibrant. No phase transformation was observed in this study. A third-order Birch–Murnaghan equation of state was used to fit the pressure–volume data. The fitting gives a volume of V 0=802.8±0.2 Å3, an isothermal bulk modulus of K T =249±12 GPa, and first pressure derivative of K T =3.2±1.3. If K T is fixed as 4, K T is obtained as 241.8±2.6 GPa. Compared with zirconate or titanate pyrochlores, MgZrSi2O7 shows a smaller compressibility due to a larger cation radii ratio (r Mg,  Zr /r Si).

关键词Pyrochlore mgzrsi2o7 high Pressure x-ray Diffraction equation Of State
收录类别SCI
文献类型期刊论文
条目标识符http://ir.gyig.ac.cn/handle/42920512-1/11105
专题地球内部物质高温高压实验室
作者单位1.Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education; School of Earth and Space Sciences, Peking University, Beijing, 100871, People's Republic of China
2.Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550002, People's Republic of China
3.Institute for Study of the Earth's Interior, Okayama University, Misasa, Tottori, 682-0193, Japan
4.Japan Synchrotron Radiation Research Institute, Sayo, Hyogo, 679-5198, Japan
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Shuangmeng Zhai;Shuangming Shan;Daisuke Yamazaki;Ken-ichi Funakoshi. Compressibility of pyrochlore-type MgZrSi2O7 determined by in situ X-ray diffraction in a large-volume high pressure apparatus[J]. High Pressure Research,2013,33(1):1-7.
APA Shuangmeng Zhai;Shuangming Shan;Daisuke Yamazaki;Ken-ichi Funakoshi.(2013).Compressibility of pyrochlore-type MgZrSi2O7 determined by in situ X-ray diffraction in a large-volume high pressure apparatus.High Pressure Research,33(1),1-7.
MLA Shuangmeng Zhai;Shuangming Shan;Daisuke Yamazaki;Ken-ichi Funakoshi."Compressibility of pyrochlore-type MgZrSi2O7 determined by in situ X-ray diffraction in a large-volume high pressure apparatus".High Pressure Research 33.1(2013):1-7.
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