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Phenol-formaldehyde resin route to the synthesis of several iron group transition metal phosphides
Hanchuan Zhao;  Yan Shi;  Zhiwei Yao;  Liying Liang;  Siqi Wang;  Qingyou Liu;  Baojiang Jiang;  Yue Sun
2019
Source PublicationPhosphorus, Sulfur, and Silicon and the Related Elements
Pages1-7
Abstract

A series of iron, cobalt and nickel metal phosphides of chemical formula FexP, Co2P and Ni2P with high specific surface areas of 331.1, 294.2 and 228.0 m2 g1 , respectively, was firstly synthesized by phenol-formaldehyde resin route. It was found that the as-prepared Co2P and Ni2P samples synthesized using phenol-formaldehyde resin as a carbon source showed much higher BET surface areas than those prepared using other carbon sources reported before, including cinnamic strong alkali anion exchange resin, p-phenylenediamine and hexamethylenetetramine. This phenol-formaldehyde resin route was proved to be as universal as traditional H2 reduction method.

KeywordFexp Co2p Ni2p Phenolformaldehyde Resin Transition Metal Phosphide
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.gyig.ac.cn/handle/42920512-1/10550
Collection地球内部物质高温高压实验室
Affiliation1.Department of Petrochemical Engineering, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, P.R. China
2.Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, P.R. China
3.Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People’s Republic of China, Heilongjiang University, Harbin, P.R. China
Recommended Citation
GB/T 7714
Hanchuan Zhao;Yan Shi;Zhiwei Yao;Liying Liang;Siqi Wang;Qingyou Liu;Baojiang Jiang;Yue Sun. Phenol-formaldehyde resin route to the synthesis of several iron group transition metal phosphides[J]. Phosphorus, Sulfur, and Silicon and the Related Elements,2019:1-7.
APA Hanchuan Zhao;Yan Shi;Zhiwei Yao;Liying Liang;Siqi Wang;Qingyou Liu;Baojiang Jiang;Yue Sun.(2019).Phenol-formaldehyde resin route to the synthesis of several iron group transition metal phosphides.Phosphorus, Sulfur, and Silicon and the Related Elements,1-7.
MLA Hanchuan Zhao;Yan Shi;Zhiwei Yao;Liying Liang;Siqi Wang;Qingyou Liu;Baojiang Jiang;Yue Sun."Phenol-formaldehyde resin route to the synthesis of several iron group transition metal phosphides".Phosphorus, Sulfur, and Silicon and the Related Elements (2019):1-7.
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