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阿尔泰造山带古生代地层地球化学特征及其对沉积环境和稀有金属背景的制约
沈瑞峰
导师张辉
2014
学位授予单位中国科学院研究生院
学位授予地点北京
学位名称硕士
学位专业矿物学、岩石学、矿床学
关键词阿尔泰造山带 古生代地层 地球化学特征 沉积环境 伟晶岩 稀有金属物源
摘要阿尔泰造山带是中亚造山带的重要组成部分。前人基于对该地区岩浆岩的研究,对该造山带的构造演化和地壳生长历史取得了很多重要的认识。但已有的研究缺乏了对该区域广泛分布的古生代地层的研究。阿尔泰造山带发育的伟晶岩脉有十余万条,但只有其中的小部分是我国重要稀有金属来源的稀有金属伟晶岩。已有研究对稀有金属物质来源还没有一个统一的认识。因此,本文拟通过采集大量阿尔泰造山带古生代地层代表性样品,系统地进行岩石地球化学特征研究,对该造山带在古生代所处的沉积构造环境进行制约,同时根据不同时代地层样品中的稀有金属背景值,对阿尔泰稀有金属伟晶岩的可能物源进行探讨。 阿尔泰造山带较为广泛地分布了前寒武纪、古生代、中生代的地层。其中分布最为广泛的古生代地层主要有中奥陶统哈巴河群、中志留统库鲁姆提群、下泥盆统康布铁堡组、中泥盆统阿勒泰组、上泥盆统-下石炭统库马苏组以及下石炭统红山嘴组。岩性以云母片岩、石英片岩、变粒岩和少量变碎屑岩为主,部分经历了低绿片岩-高角闪岩相的变质作用。 对阿尔泰造山带不同古生代地层浅变质碎屑岩的地球化学研究表明,其原岩主要为泥质和砂质沉积岩,包含少量火山岩或火成岩的风化剥蚀的产物。它们的蚀变化学指数(CIA)特征表明,形成哈巴河群 (CIA=50~70)、库鲁姆提群 (CIA=57~68)、康布铁堡组(CIA=50~67)、阿勒泰组 (CIA=52~60)和红山嘴组 (CIA=66~68)的源区物质经历了相对寒冷、干燥条件下较弱的化学风化作用,而形成库马苏组 (CIA=71~79)的源区物质可能经历了温暖-炎热、湿润-潮湿条件下中等-强烈化学风化作用。它们的成分变异指数(ICV)总体>1.0 (主要分布于1.04~1.61),指示碎屑岩的成熟度较差,代表活动构造环境直接沉积的产物。在K2O-Rb、La/Sc-Sc/Th和La/Th-Hf图解中,它们落入酸性岛弧区域,表明其碎屑物质可能来源于酸性岛弧区域。它们的主、微量元素组成显示,哈巴河群、库鲁姆提群、康布铁堡组、阿勒泰组的碎屑沉积岩形成于大陆岛弧背景,而库马苏组、红山嘴组的形成则与大陆岛弧-活动大陆边缘背景有关。 阿尔泰造山带地层样品的稀有金属Be、Nb、Ta元素含量与上地壳平均含量无显著性差异 (富集系数~1),而它们(特别是前寒武系地层)的Li含量则明显偏高 (富集系数为1.68~3.41),说明其可能为阿尔泰地区稀有金属伟晶岩矿床提供了物源。 综上所述,阿尔泰造山带古生代地层的碎屑物质可能来源于经弱化学风化作用的酸性岛弧岩石,沉积于与活动大陆边缘相关的大陆岛弧盆地。这些地层(特别是前寒武系地层)中相对富集稀有金属Li。因此,我们认为中亚造山带在三叠纪发生了陆-陆碰撞造山作用,构造体制由挤压转换为伸展,可能导致该地区富含稀有金属Li的加厚地壳物质发生减压熔融,形成了阿尔泰造山带中的稀有金属伟晶岩。
其他摘要The Altay orogenic belt is an important part of the Central Asian Orogenic Belt. Many important understandings on the history of tectonic evolution and crustal growth of the belt have been achieved through previous studies on magmatic rocks in the belt. There is lack of works on those widely outcropped Paleozoic strata in the region among previous studies. Although there are more than ten thousand of pegmatite dikes in the Altay orogenic belt, only a small amount of them are rare metal-bearing pegmatite dikes which are important sources of rare metal in our country. No consistent understanding on the source of rare metals in pegmatite dikes has been obtained. Therefore, after collecting a large amount of representative samples of the Paleozoic strata in the Altay orogenic belt, a systematical study on the petro-geochemical characteristics of those strata in various ages has been undertaken, the Paleozoic sedimentary tectonic environment of the belt has been constrained, the source of rare metals in mineralized pegmatite of the belt has been discussed after analyzing the contents of rare metals in various strata in the region. There are Precambrian, Paleozoic, and Mesozoic strata, which are relative widely distributed, in the Altay orogenic belt. The Paleozoic strata, which are most widely distributed in the belt, mainly include the Lower Ordovician Habahe Group, Middle Silurian Kulumuti Group, Lower Devonian Kangbutiebao Formation, Middle Devonian Altay Formation, Upper Devonian-Lower Carboniferous Kumasu Formation, and Lower Carboniferous Hongshanzui Formation, with major metasedimentary rocks, such as mica schist, quartz schist, leptynite, and meta-clastic rocks. Some strata had experienced metamorphism from greenschist to amphibolite. The geochemical study of lowly metamorphosed clastic rocks from various Palaeozoic strata in the Altay orogenic belt shows that they were mainly originated from mud and sandy sedimentary rocks, containing a small amount of the weathering product of volcanic rocks. The characteristics of their chemical indexes of alteration (CIA) show that the Habahe Group (CIA of 50-70), Kulumuti Group (CIA of 57-68), Kangbutiebao Formation (CIA of 50-67), Altay Formation (CIA of 52-60) and Hongshanzui Formation (CIA of 66-68) were sourced from weak chemically weathered rocks under the relatively cold, dry condition, whereas the Kumasu Formation (CIA of 71-79) was sourced from medium to strong chemically weathered rocks under the warm-hot, humid - wet conditions. Their indexes of compositional variability (ICV) are generally higher than 1.0 with variation mainly from 1.04 to 1.61, indicating a poor maturity for clastic rocks which were directly deposited in active tectonic environment. Their compositions are plotted into fields of acidic islane arc in diagrams of K2O versus Rb, La/Sc versus Sc/Th, and La/Th versus Hf, indicating that their clastic materials could be sourced from acidic island arc. Their compositions of major and trace elements show that the Habahe and Kulumuti groups, and Kangbutiebao and Altay formations were deposited in the environment of continental island arc, whereas the Kumasu and Hongshanzui formations were deposited in the junction between the continental island arc and active continental margin. The contents of Be, Nb and Ta of strata in the Altay orogenic belt are similar to those of the average of the upper crust, with the concentration coefficients of about 1, while the Li contents of strata, especially the Precambrian Kemuqi and Supute groups, are obviously higher than the average of the upper crust, with the concentration coefficients varying from 1.68 to 3.41. This indicates that the Precambrian strata could partly be source of the rare metal-bearing pegmatite. In general, the detrital materials of Paleozoic strata in the Altay orogenic belt could be sourced from weak chemically weathered rocks of the acidic island arc, deposited in the continental island arc basin related to a
学科领域地球深部物质与流体作用地球化学
语种中文
文献类型学位论文
条目标识符http://ir.gyig.ac.cn/handle/352002/5902
专题研究生_研究生_学位论文
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沈瑞峰. 阿尔泰造山带古生代地层地球化学特征及其对沉积环境和稀有金属背景的制约[D]. 北京. 中国科学院研究生院,2014.
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