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河南小秦岭大湖金-钼矿床地球化学及其矿床成因
其他题名Ore Geochemistry And Ore Genesis Of Dahu Gold-Molybdenum Deposit In The Xiaoqinling Gold Field, Henan Province
倪智勇
2009-05-31
学位授予单位中国科学院地球化学研究所
学位授予地点地球化学研究所
学位名称博士
关键词大湖金-钼矿床 印支期成矿作用 弧后转换带 地球化学 同位素 流体包裹体 成矿年代学
摘要秦岭造山带是华北与扬子两大古板块的接合带,在空间上,自北而南,秦岭造山带可分为华北板块南缘(华熊地块)、北秦岭造山带、南秦岭造山带和扬子板块北缘等4个构造单元。小秦岭金矿田位于华熊地块北缘,是国内外学者共识的造山型金矿田,河南灵宝大湖金-钼矿床位于小秦岭金矿田,属断控脉状矿床。大湖金-钼矿床最先正是以金矿床进行勘查的,其黄金储量28t,平均品位8.7g/t。随着开采深度的加大,部分含金石英脉向深部转变为辉钼矿-石英脉,目前探明钼资源量已达中型规模。 本论文主要从区域地质背景、矿床地质特征、元素地球化学、同位素地球化学、流体包裹体地球化学、矿床年代学及成矿机理等角度对大湖金-钼矿床进行了较为系统的研究,主要获得如下认识: 成矿过程经历3个阶段:早阶段为黄铁矿-石英脉,遭受变形、破碎,应形成于挤压或压剪过程;中阶段为细粒的辉钼矿-黄铁矿-石英网脉,贯入到早阶段黄铁矿或石英矿物的裂隙(可呈共轭状),应形成于剪切环境;晚阶段石英-碳酸盐细脉具梳状构造,充填于张性或张扭性裂隙。 大湖金-钼矿床的金属硫化物ISr=0.70470-0.71312,平均0.70854;(143Nd/144Nd)i=0.51143-0.51215,平均0.51162;(206Pb/204Pb)i=17.033-17.285,(207Pb/204Pb)i=15.358-15.438,(208Pb/204Pb)i = 37.307-37.582。其围岩太华群样品平均值ISr=0.72294,(143Nd/144Nd)i=0.51107,(206Pb/204Pb)i=17.127-18.392,(207Pb/204Pb)i =15.416-15.604,(208Pb/204Pb)i=37.498-37.814,它们的平均值分别是17.547,15.470,37.616。通过金属硫化物及围岩太华群的对比,可以看出,成矿物质具有太华群和深部地幔混合的特征。 通过对不同阶段的含矿石英脉中的流体包裹体特征研究表明,早阶段只发育CO2-H2O型流体包裹体;中阶段流体包裹体类型复杂,有纯CO2型、CO2-H2O型、H2O-NaCl型和含子晶包裹体,指示流体沸腾作用强烈;而晚阶段只发育水溶液包裹体。早、中、晚3个阶段的流体包裹体均一温度分别集中在400-500℃、290-470℃、220-260℃;估计的早、中阶段流体的最低捕获压力分别为138-331MPa和78-237MPa,对应于成矿深度分别为13.8-11.0km和7.8-8.0km。早、中阶段的压力反应出静岩压力到静水压力的转变。成矿温度和压力明显高于浅部含金石英脉的成矿温度120-310℃,成矿压力100-150MPa。与野外观察到的“上金下钼”的空间关系一致。 大湖金-钼矿床辉钼矿-石英脉Re-Os同位素模式年龄较集中,介于215.4±5.4-255.6±9.6Ma,Re-0s等时线年龄为218±41Ma(MSWD=38,2σ误差),表明大湖金-钼矿的辉矿化形成于印支期。 三叠纪末,随着古秦岭洋的逐渐封闭,处在弧后转换带的深部岩石在挤压作用下发生变质脱水而形成初始成矿流体,成矿流体沿断裂带(韧性剪切带)向上迁移而引起大湖钼矿床成矿系统的发育。随着区域构造环境由挤压转为伸展,区域的变质脱水更强,形成大量成矿流体,变质流体上侵为浅层流体循环提供了的热能,而浅层构造也因减压扩容而为流体循环提供了通道,这无疑有利于浅层流体循环和混入成矿系统。同时,增温和减压也有利于成矿流体发生沸腾。因此,充足的流体、热以及强烈的流体沸腾等,势必导致发生最为强烈的成矿物质快速沉淀作用。随着挤压作用的减弱,伸展作用的增强,区域热异常消失,地壳深部组分发生亏损,流体以浅源大气降水占主导,成矿作用迅速衰竭,形成石英-碳酸盐网脉,对成矿作用贡献减弱。总之,通过对大湖金钼矿床研究表明,大湖金钼矿床形成于由挤压转向伸展的构造背景,这与矿床地质的特征一致。
其他摘要The Qingling orogen belt is the suture of North China plate and Yangtze plate, it can be divided into 4 tectonic units: the southern margin of North China plate (Huashan-Xiong’ershan block), North Qinling orogen belt, South Qinling orogen belt and the northern margin of Yangtze plate in spatially. The XiaoQinling is located in the southern margin of Huashan-Xiong’ershan block, and the XaioQinling gold field is the orogenic gold field that has been agreed with the domestic and foreign scholars. The Dahu Au-Mo deposit, Lingbao County, Henan Province is a typical fault-controlled lode deposit that occurred in the north part of Xiaoqinling gold field. The Dahu Au-Mo deposit is explored for gold deposit at first, its Au reserve reachs to 28t, average grade is 8.7g/t. Part of Au-bearing quartz veins change to molybdenum-quartz veins along with the exploring depth, the ascertained Mo reserve reach to medium size deposit at present. The author has systematically studied the Dahu Au-Mo deposit in various aspects including regional geological setting, deposit geology, elemental geochemistry, isotope geochemistry, fluid inclusions geochemistry , geochronology and ore-forming mechanism. The main result is obtained as following: The ore-forming process can be divided into three stages. The early stage is characterized by pyrite-quartz veins, in which minerals were structurally deformed and broken, indicating that they formed in a compression or compressive distortion setting. The middle stage is characterized by molybdenite-pyrite-quartz stockworks (mostly coaxial or conjugated) infilling the cracks of the early-stage minerals such as pyrite and quartz, suggesting that it occurred in a tensional shear setting. The late stage is characterized by extensional open-space filling quartz-carbonate veinlets with comb-like texture. The ISr of the metal sulfide of the Dahu Au-Mo deposit vary from 0.70470 to 0.71312, its average is 0.70854. Its (143Nd/144Nd)i vary from 0.51143 to 0.51215, its average is 0.51162. Its (206Pb/204Pb)i, (207Pb/204Pb)i, (208Pb/204Pb)i vary from 17.033 to 17.285, from 15.358 to 15.438, from 37.307 to 37.582 respectively. The average ISr, (143Nd/144Nd)i of wall rock(Taihua group) is 0.72294, 0.51107 respectively. Its (206Pb/204Pb)i vary form 17.127-18.392(average 17.547), (207Pb/204Pb)i vary from 15.416 to 15.604 (average 15.470), (208Pb/204Pb)i vary from 37.498 to 37.582(average 37.440) respectively. The ore-forming materials are characteristic in the mixture of Taihua Group and mantle by the comparison of Sr, Nd, Pb isotope of metal sulfide and Taihuo Group. Various inclusions in sulfide-bearing quartz veins have been identified through microthermometry and Laser Raman microspectroscopy. It can be identified: The early-stage minerals only contain CO2-H2O inclusions, whereas the late-stage minerals only contain H2O-NaCl inclusions. Both the H2O-NaCl and CO2-H2O inclusions, together with pure CO2 and daughter mineral-bearing inclusions can be observed in the middle-stage minerals, implying that strong fluid-boiling occurred in this stage. Homogenization temperatures of fluid inclusions range from 400℃ to 500℃ for the early stage, from 290℃ to 470℃ for the middle stage, and from 220℃ to 260℃ for the late stage. The trapping pressure are estimated at least to be 138-331 MPa for the early stage and 78-237 MPa for the middle stage, respectively, corresponding to the ore-forming depth of 13.8-11.0 km and 7.8-8.0 km, respectively, implying the pressure change from lithostatic to hydrostatic. The ore-forming temperature and pressure is higher than the temperature and pressure of Au-bearing quartz, its ore-forming temperature and pressure is 120-310℃, 100-150MPa respectively. It is consistent with the spatial relation of Au and Mo by the observation. The molybdenite of Dahu Au-Mo deposit Re-Os isotopic model age vary from 215.4±5.4 to 255.6±9.6, the isochron age is 218±41Ma (2σ, MSWD=38), this shows that the Mo mineralization occured in Indosinian. At the later Triassic, along with the ancient Qinling ocean closed, the deeper rocks which located in the arc-back transition belt dehydrated under the compression to form the initial mineralization fluid. The mineralization fluid transfered upward alone the fracture(shear zone) formed the Dahu molybdenum ore deposit mineralization system. Along with the transition from compression to extention, regional thermal anomaly reached to maximum, the region metamorphic dehydration was stronger, formed the massive mineralization fluid, the metamorphic fluid provided the heat energy for the shallow fluid circulation, and the shallow tectonic also provided the channel for the fluid circulation because of the reduced pressure, this is advantage for the shallow fluid circulated and mixed in the mineralization system definitely. Simultaneously, increased temperature and the reduced pressure are also advantageous in the mineralization fluid boiling.Therefore, the sufficient fluid, the heat and the intense fluid boiling would cause the most intense mineralization material fast precipitation inevitably. Along with compression weakening, the extension enhancement, region thermal anomaly vanishing, the deeper fluid loss, the shallow source atmosphere fluid is main fluid, the mineralization rapid declined, formed the quartz - carbonate net-vein, it contributed to the mineralization weakly. In a word, the fluid inclusion research indicated that the Dahu gold molybdenum ore deposit forms in the transition from compression to extension, this is consistent with the ore deposit geology characteristic.
页数109
语种中文
文献类型学位论文
条目标识符http://ir.gyig.ac.cn/handle/352002/3456
专题研究生_研究生_学位论文
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倪智勇. 河南小秦岭大湖金-钼矿床地球化学及其矿床成因[D]. 地球化学研究所. 中国科学院地球化学研究所,2009.
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