矿床地球化学国家重点实验室知识库

We present a systematic geochronological and geochemical study on ca 800–760 Ma volcanic rocks in the eastern part of the Jiangnan orogen. The Xucun composite dykes are dated at ca 805 Ma; the mafic components have OIB-like trace-element patterns and positive anomalies in Zr and Hf. The least-contaminated sample has relatively depleted Nd isotopic features, suggesting the Xucun mafic dykes may have been generated from the partial melting of OIB-like asthenosphere with later crustal contamination. The Xucun felsic dykes have decoupled Nd–Hf isotopes, and the Hf-isotope compositions of zircons indicate that the dykes may be derived from the partial melting of the early Neoproterozoic juvenile crustal materials, with minor incorporation of Paleoproterozoic crustal components. The ca 800–790 Ma Shangshu volcanics include two compositional series: calc-alkaline and tholeiitic. The Shangshu calc-alkaline volcanics in the Minjiawu area have low abundances of LILE, HFSE and high Na₂O contents and Sr/Y ratios, similar to adakitic rocks. The evident arc-like geochemical features and radiogenic Nd isotopes (ɛ_Nd(t) values of +3.7 to +4.8) suggest that these rocks may have been generated from the partial melting of juvenile lithospheric mantle metasomatized by Na-rich melts released from the subducted slab. The tholeiitic mafic rocks from the Shangshu bimodal volcanics represent two different magma sources. The partial melting of metasomatized lithospheric mantle led to the formation of arc-like basalts with low TiO₂ contents, negative anomalies in Zr and Hf, and high values of Mg^# and ɛ_Nd(t) (+6.2), whereas the partial melting of asthenospheric mantle generated volcanic rocks with high TiO₂ contents and low positive ɛ_Nd(t) (+1.4 to +2.7), without negative anomalies of Nb, Ta, Zr and Hf. The Shangshu felsic rocks were formed by the reworking of early Neoproterozoic juvenile arc crustal materials. The ca 760 Ma mafic rocks from the Puling bimodal volcanics generally have low TiO₂ contents (<0.9 wt%), nearly flat REE distributions and arc-like trace-element patterns. They may have been generated from the high-degree partial melting of metasomatized lithospheric mantle. One sample has a high TiO₂ content (2.41 wt%) and high ɛ_Nd(t) (+6.2), with overall OIB-like trace-element patterns, implying the local partial melting of asthenospheric mantle. The occurrence of significant volumes of bimodal volcanics in the eastern part of the Jiangnan orogen suggests an extensional setting in the period ca 800–760 Ma. The evident partial melting of newly-metasomatized lithospheric mantle and subordinate partial melting of asthenosphere suggest that post-orogenic extension shortly after the Neoproterozoic orogenesis may be a better explanation for the genesis of the mid-Neoproterozoic magmatic rocks in the eastern part of the Jiangnan orogen. Post-orogenic extension may be diachronous along the whole orogenic belt, and probably has no direct relationship with the Rodinia rifting event. A more detailed model is presented to illustrate the evolution of the eastern part of the Jiangnan orogen.