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In situ Investigation of the Valence States of Iron-bearing Phases in Chang'E-5 Lunar Soil using FIB, AES, and TEM-EELS Techniques
Bing Mo; Zhuang Guo; Yang Li; Dan Zhu; Xiaojia Zeng; Xiongyao Li; Jianzhong Liu; Yanxue Wu
2022
Source PublicationAtomic Spectroscopy
Volume43Issue:1Pages:53-59
Abstract

Nanophase iron (np-Fe0 ) is a major product of space weathering and its presence significantly alters the reflectance spectral characteristics of lunar soil. Previous studies have established that the np-Fe0 particles originate from the reduction of ferrous ions in the plasma, in-situ decomposition of olivine and pyroxene, and disproportionation of ferrous ions in solid ferrosilicates. In this study, sample charging effects were eliminated and in situ nanoscale valence state analysis of iron-bearing phases in Chang’E-5 lunar soil was conducted by combining focused ion beam (FIB) microscopy, Auger electron spectroscopy (AES), and transmission electron microscopy-electron energy loss spectroscopy (TEM-EELS) techniques. The results indicate that the contents and valence states of iron in the np-Fe0 particles, amorphous matrix, and ferrosilicates differ. The np-Fe0 particles were found to be composed of pure metallic iron, whereas ferrous and ferric iron ions were present in olivine crystals and the amorphous matrix, respectively. The discovery of both metallic and ferric iron in the amorphous matrix of Chang’E-5 lunar soil offers new insights regarding the disproportionation reaction of Fe2+ on the lunar surface. This study demonstrates that the combination of FIB, AES, and TEMEELS is an effective and precise approach for analyzing the valence states of iron-bearing phases in lunar soil, which can be extended to other extraterrestrial samples and other multivalent elements.

DOI10.46770/AS.2022.014
Indexed BySCI
Language英语
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.gyig.ac.cn/handle/42920512-1/13535
Collection月球与行星科学研究中心
矿床地球化学国家重点实验室
天体地球化学研究组
Affiliation1.Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, P.R. China
2.State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, P.R. China
3.Center for Excellence in Comparative Planetology, Chinese Academy of Sciences, Hefei 230026, P.R. China
4.College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, P.R. China
Recommended Citation
GB/T 7714
Bing Mo,Zhuang Guo,Yang Li,et al. In situ Investigation of the Valence States of Iron-bearing Phases in Chang'E-5 Lunar Soil using FIB, AES, and TEM-EELS Techniques[J]. Atomic Spectroscopy,2022,43(1):53-59.
APA Bing Mo.,Zhuang Guo.,Yang Li.,Dan Zhu.,Xiaojia Zeng.,...&Yanxue Wu.(2022).In situ Investigation of the Valence States of Iron-bearing Phases in Chang'E-5 Lunar Soil using FIB, AES, and TEM-EELS Techniques.Atomic Spectroscopy,43(1),53-59.
MLA Bing Mo,et al."In situ Investigation of the Valence States of Iron-bearing Phases in Chang'E-5 Lunar Soil using FIB, AES, and TEM-EELS Techniques".Atomic Spectroscopy 43.1(2022):53-59.
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