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P-V-T relations of γ-Ca3(PO4)2 tuite determined by in situ X-ray diffraction in a large-volume high-pressure apparatus
Shuangmeng Zhai;   Daisuke Yamazaki;   Weihong Xue;   Lijin Ye;   Chaowen Xu;   Shuangming Shan;   Eiji Ito;   Akira Yoneda;   Takashi Yoshino;   Xinzhuan Guo;   Akira Shimojuku;   Noriyoshi Tsujino;   Ken-Ichi Funakoshi
2012
Source PublicationAmerican Mineralogist
Volume98Issue:10Pages:1811-1816
Abstract

Tuite, γ-Ca3(PO4)2, is regarded as an important phosphate mineral in the deep mantle playing a crucial role as a host for rare earth elements, large ion lithophile elements, and phosphorus. In this study we report the thermoelastic properties of synthetic γ-Ca3(PO4)2 at simultaneously high pressures and temperatures of up to 35.4 GPa and 1300 K, respectively, as determined by means of in situ energy-dispersive X-ray diffraction in a large-volume multi-anvil apparatus. The pressure-volume-temperature data obtained for γ-Ca3(PO4)2 were fitted by the high-temperature Birch-Murnaghan equation of state to yield V0 = 447.4(4) Å3KT0 = 100.8(18) GPa, KT0 = 5.74(13), (∂KT/∂T)P = −0.020(1) GPa/K, and αT = 3.26(18) × 10−5 + 1.76(24) × 10−8T. In addition, fitting the present data to the Mie-Grüneisen-Debye equation of state gives γ0 = 1.35(6), Θ0 = 944(136) K, and q = 0.37(29). Based on the thermoelastic properties obtained in our study, the density profiles of γ-Ca3(PO4)2 tuite along typical cold and hot slab geotherms were calculated and are compared with those of the coexisting silicate minerals in subducting mid-ocean ridge basalt.

KeywordΓ-ca3(Po4)2 Tuite in Situ X-ray Diffraction thermal Equation Of State thermoelastic Properties
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.gyig.ac.cn/handle/42920512-1/10966
Collection地球内部物质高温高压实验室
Affiliation1.Key Laboratory of Orogenic Belts and Crustal Evolution, MOE; School of Earth and Space Sciences, Peking University, Beijing 100871, China
2.Institute for Study of the Earth’s Interior, Okayama University, Misasa, Tottori 682-0193, Japan
3.Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou 550002, China
4.Japan Synchrotron Radiation Research Institute, Sayo, Hyogo 679-5198, Japan
Recommended Citation
GB/T 7714
Shuangmeng Zhai; Daisuke Yamazaki; Weihong Xue; Lijin Ye; Chaowen Xu; Shuangming Shan; Eiji Ito; Akira Yoneda; Takashi Yoshino; Xinzhuan Guo; Akira Shimojuku; Noriyoshi Tsujino; Ken-Ichi Funakoshi. P-V-T relations of γ-Ca3(PO4)2 tuite determined by in situ X-ray diffraction in a large-volume high-pressure apparatus[J]. American Mineralogist,2012,98(10):1811-1816.
APA Shuangmeng Zhai; Daisuke Yamazaki; Weihong Xue; Lijin Ye; Chaowen Xu; Shuangming Shan; Eiji Ito; Akira Yoneda; Takashi Yoshino; Xinzhuan Guo; Akira Shimojuku; Noriyoshi Tsujino; Ken-Ichi Funakoshi.(2012).P-V-T relations of γ-Ca3(PO4)2 tuite determined by in situ X-ray diffraction in a large-volume high-pressure apparatus.American Mineralogist,98(10),1811-1816.
MLA Shuangmeng Zhai; Daisuke Yamazaki; Weihong Xue; Lijin Ye; Chaowen Xu; Shuangming Shan; Eiji Ito; Akira Yoneda; Takashi Yoshino; Xinzhuan Guo; Akira Shimojuku; Noriyoshi Tsujino; Ken-Ichi Funakoshi."P-V-T relations of γ-Ca3(PO4)2 tuite determined by in situ X-ray diffraction in a large-volume high-pressure apparatus".American Mineralogist 98.10(2012):1811-1816.
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