环境地球化学国家重点实验室知识库

The morphology, trace-element composition and geochronology of 43 zircon grains from two monzogranite samples from the Northeast Xing’an Block, northeastern China, were determined using cathodoluminescence imaging and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Three morphological subtypes (S3, S8 and S9) are recognized in the zircon grain samples, and subtype S8 is dominant, reflecting a calc-alkaline, moderately aluminous, high-pressure crystallization medium and a crystallization temperature of 700 ± 50 °C. The zircon grains are characterized by oscillatory zoning, relatively high Th/U ratios (0.3–1.0), steep chondrite-normalized rare-earth element patterns, high Hf contents (>9000 ppm), positive Ce (Ce/Ce* = 4.84 to 2914) and negative Eu (Eu/Eu* = 0.24 to 0.90) anomalies, indicating a magmatic source. The ²⁰⁶Pb/²³⁸U ages of the two monzogranite samples are 180 ± 1 and 181 ± 1 Ma, respectively, implying an Early Jurassic emplacement age for the intrusion. The disparate geochemical behaviors of Hf, Th, and Nb within the zircons, as well as the U/Yb, Nb/Yb, Th/U, Nb/Hf, Th/Nb, and Hf/Th ratios, suggest a continental-crust source in a compressional-magmatic-arc or orogenic-tectonic setting, and a calc-alkaline parent magma. All of the grains show relatively high Ce⁴⁺/Ce³⁺ ratios, suggesting that they were derived from an oxidized magma, which favors enrichment of Cu-Mo elements in the granite porphyry.