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Crystal chemistry of Eu-bearing tuite synthesized at high-pressure and high-temperature conditions
Shuangmeng Zhai;  Hexiong Yang;  Weihong Xue;  Eugene Huang;  Daisuke Yamazaki;  Shaunna M. Morrison;  Robert T. Downs
2019
Source PublicationPhysics and Chemistry of Minerals
Volume46Pages:157–163
Abstract

Tuite, γ-Ca3(PO4)2, is a potential host for rare-earth elements in the deep mantle. Eu-bearing tuite single crystals with chemical formulas of Ca2.93Eu0.04(PO4)2 and Ca2.88Eu0.07Na0.06(PO4)2 were synthesized at 16 GPa and 1600 °C, and their structures were investigated at room temperature with single-crystal X-ray diffraction. The structure refinements of Eu-bearing tuite indicate the preference of Eu3+ for the smaller 6-coordinated Ca1 site with a coupled vacancy due to the substitution of 2Eu3+ + □ → 3 Ca2+. In NaEu-bearing tuite, both Eu3+ and Na+ occupy the smaller 6-coordinated Ca1 site according to the coupled substitution of Eu3+ + Na+ → 2 Ca2+. The presence of Na results in more Eu2O3 in NaEu-bearing tuite, because the coupled substitution is energetically more favorable. REE-bearing tuite could be found on the Moon and the deep Earth’s mantle as a consequence of REE-bearing apatite or/and merrillite transformation under high-pressure and high-temperature conditions.

KeywordEu-bearing Tuite Γ-ca3(Po4)2 Crystal Structure Single-crystal X-ray Diffraction
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.gyig.ac.cn/handle/42920512-1/10430
Collection地球内部物质高温高压实验室
Affiliation1.Key Laboratory of High-temperature and High-pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, Guizhou, China
2.Department of Geosciences, University of Arizona, Tucson, AZ 85721-0077, USA
3.Center for High Pressure Science and Technology Advanced Research, Shanghai 201203, China
4.Institute for Planetary Materials, Okayama University, Misasa, Tottori 682-0193, Japan
5.Geophysical Laboratory, Carnegie Institution for Science, Washington, DC 20015, USA
Recommended Citation
GB/T 7714
Shuangmeng Zhai;Hexiong Yang;Weihong Xue;Eugene Huang;Daisuke Yamazaki;Shaunna M. Morrison;Robert T. Downs. Crystal chemistry of Eu-bearing tuite synthesized at high-pressure and high-temperature conditions[J]. Physics and Chemistry of Minerals,2019,46:157–163.
APA Shuangmeng Zhai;Hexiong Yang;Weihong Xue;Eugene Huang;Daisuke Yamazaki;Shaunna M. Morrison;Robert T. Downs.(2019).Crystal chemistry of Eu-bearing tuite synthesized at high-pressure and high-temperature conditions.Physics and Chemistry of Minerals,46,157–163.
MLA Shuangmeng Zhai;Hexiong Yang;Weihong Xue;Eugene Huang;Daisuke Yamazaki;Shaunna M. Morrison;Robert T. Downs."Crystal chemistry of Eu-bearing tuite synthesized at high-pressure and high-temperature conditions".Physics and Chemistry of Minerals 46(2019):157–163.
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