In-situ LA-ICP-MS trace elemental analyses of magnetite: Fe-Ti-(V) oxide-bearing mafic-ultramafic layered intrusions of the Emeishan Large Igneous Province, SW China

	In-situ LA-ICP-MS trace elemental analyses of magnetite: Fe-Ti-(V) oxide-bearing mafic-ultramafic layered intrusions of the Emeishan Large Igneous Province, SW China
	Ping-Ping Liu; Mei-fu Zhou; Wei-terry Chen; Jian-feng Gao; Xiao-wen Huang
	2015
发表期刊	Ore Geology Reviews
卷号	65 期号:6 页码:853-871
摘要	The Taihe, Baima, Hongge, Panzhihua and Anyi intrusions of the Emeishan Large Igneous Province (ELIP), SW China, contain large magmatic Fe-Ti-(V) oxide ore deposits. Magnetites from these intrusions have extensive trellis or sandwich exsolution lamellae of ilmenite and spinel. Regular electron microprobe analyses are insufficient to obtain the primary compositions of such magnetites. Instead, laser ablation ICP-MS uses large spot sizes (similar to 40 mu m) and can produce reliable data for magnetites with exsolution lamellae. Although magnetites from these deposits have variable trace element contents, they have similar multi-element variation patterns. Primary controls of trace element variations of magnetite in these deposits include crystallography in terms of the affinity of the ionic radius and the overall charge balance, oxygen fugacity, magma composition and coexisting minerals. Early deposition of chromite or Cr-magnetite can greatly deplete magmas in Cr and thus Cr-poor magnetite crystallized from such magmas. Co-crystallizing minerals, olivine, pyroxenes, plagioclase and apatite, have little influence on trace element contents of magnetite because elements compatible in magnetite are incompatible in these silicate and phosphate minerals. Low contents and bi-modal distribution of the highly compatible trace elements such as V and Cr in magnetite from Fe-Ti oxide ores of the ELIP suggest that magnetite may not form from fractional crystallization, but from relatively homogeneous Fe-rich melts. QUILF equilibrium modeling further indicates that the parental magmas of the Panzhihua and Baima intrusions had high oxygen fugacities and thus crystallized massive and/or net-textured Fe-Ti oxide ores at the bottom of the intrusive bodies. Magnetite of the Taihe, Hongge and Anyi intrusions, on the other hand, crystallized under relatively low oxygen fugacities and, therefore, formed net-textured and/or disseminated Fe-Ti oxides after a lengthy period of silicate fractionation. Plots of Ge vs. Ga + Co can be used as a discrimination diagram to differentiate magnetite of Fe-Ti-(V) oxide-bearing layered intrusions in the ELIP from that of massif anorthosites and magmatic Cu-Ni sulfide deposits. Variable amounts of trace elements of magmatic magnetites from Fe-Ti-(P) oxide ores of the Damiao anorthosite massif (North China) and from Cu-Ni sulfide deposits of Sudbury (Canada) and Huangshandong (northwest China) demonstrate the primary control of magma compositions on major and trace element contents of magnetite.
学科领域	矿床地球化学
收录类别	SCI
语种	英语
文献类型	期刊论文
条目标识符	http://ir.gyig.ac.cn/handle/352002/6003
专题	矿床地球化学国家重点实验室_矿床地球化学国家重点实验室_期刊论文矿床地球化学国家重点实验室
推荐引用方式 GB/T 7714	Ping-Ping Liu,Mei-fu Zhou,Wei-terry Chen,et al. In-situ LA-ICP-MS trace elemental analyses of magnetite: Fe-Ti-(V) oxide-bearing mafic-ultramafic layered intrusions of the Emeishan Large Igneous Province, SW China[J]. Ore Geology Reviews,2015,65(6):853-871.
APA	Ping-Ping Liu,Mei-fu Zhou,Wei-terry Chen,Jian-feng Gao,&Xiao-wen Huang.(2015).In-situ LA-ICP-MS trace elemental analyses of magnetite: Fe-Ti-(V) oxide-bearing mafic-ultramafic layered intrusions of the Emeishan Large Igneous Province, SW China.Ore Geology Reviews,65(6),853-871.
MLA	Ping-Ping Liu,et al."In-situ LA-ICP-MS trace elemental analyses of magnetite: Fe-Ti-(V) oxide-bearing mafic-ultramafic layered intrusions of the Emeishan Large Igneous Province, SW China".Ore Geology Reviews 65.6(2015):853-871.

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