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A laser ablation ICP-MS study of platinum-group and chalcophile elements in base metal sulfide minerals of the Jinchuan Ni-Cu sulfide deposit, NW China
Lie-Meng Chen; Xie-yan Song; Leonid V. Danyushevsky; Yu-shan Wang; Yu-long Tian; Jia-fei Xiao
2015
Source PublicationOre Geology Reviews
Volume65Issue:5Pages:955-967
AbstractThe paper presents concentrations of the platinum-group and chalcophile elements in the base metal sulfides (BMS) from the Jinchuan Ni-Cu sulfide deposit determined by laser ablation-inductively coupled plasma-mass spectrometry. Mass balance calculations reveal that pentlandite hosts a large proportion of Co, Ni and Pd (>65%), and that pentlandite and pyrrhotite accommodate significant proportions of Re, Os, Ru, Rh, and Ag (similar to 35-90%), whereas chalcopyrite contains a small amount of Ag (similar to 10%) but negligible platinum-group elements. Iridium and Pt are not concentrated in the BMS and mostly occur in As-rich platinum-group minerals. The enrichments of Co, Ni, Re, Os, Ru, and Rh in pentlandite and pyrrhotite, and Cu in chalcopyrite are consistent with the fractionation of sulfide liquid and exsolution of pentlandite and pyrrhotite from the mono-sulfide solid solution (MSS). The Ir-bearing minerals exsolved from the MSS, depleting pentlandite and pyrrhotite in IL whereas sperrylite exsolved from the residual sulfide liquid on cooling. Diffusion of Pd from residual sulfide liquid into pentlandite during its exsolution from the MSS and crystallization of Pt-bearing minerals in the residual sulfide liquid resulted in the enrichment of Pd in pentlandite and decoupling between Pd and Pt in the Jinchuan net-textured and massive ores.
Subject Area矿床地球化学
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.gyig.ac.cn/handle/352002/6001
Collection矿床地球化学国家重点实验室_矿床地球化学国家重点实验室_期刊论文
Recommended Citation
GB/T 7714
Lie-Meng Chen,Xie-yan Song,Leonid V. Danyushevsky,et al. A laser ablation ICP-MS study of platinum-group and chalcophile elements in base metal sulfide minerals of the Jinchuan Ni-Cu sulfide deposit, NW China[J]. Ore Geology Reviews,2015,65(5):955-967.
APA Lie-Meng Chen,Xie-yan Song,Leonid V. Danyushevsky,Yu-shan Wang,Yu-long Tian,&Jia-fei Xiao.(2015).A laser ablation ICP-MS study of platinum-group and chalcophile elements in base metal sulfide minerals of the Jinchuan Ni-Cu sulfide deposit, NW China.Ore Geology Reviews,65(5),955-967.
MLA Lie-Meng Chen,et al."A laser ablation ICP-MS study of platinum-group and chalcophile elements in base metal sulfide minerals of the Jinchuan Ni-Cu sulfide deposit, NW China".Ore Geology Reviews 65.5(2015):955-967.
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