| Manipulating the morphology of nanoscale zero-valent iron on pumice for removal of heavy metals from wastewater |
| Tingyi Liu; Zhong-Liang Wang; Yanqiu Sun
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| 2015
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Source Publication | Chemical Engineering Journal
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Volume | 263Issue:1Pages:55-61 |
Abstract | The removal of heavy metals from wastewater is one of the most important issues for the world, especially from industrial effluents. Pumice-nanoscale zero-valent iron (P-NZVI) was successfully prepared in different experimental conditions. Meanwhile, the shape, size and distribution of NZVI on P-NZVI were evaluated using a scanning electron microscope (SEM). At the optimum condition, NZVI with a mean diameter of 20.2 nm was distributed uniformly and consistently on the surface of pumice. Freundlich isotherm analysis suggested that the surface property of P-NZVI were heterogeneous. The removal of Hg (II) and Cr (VI) by P-NZVI could be well described by pseudo-first-order kinetic model. At equilibrium q(max) of Hg (II) and Cr (VI) was 107.1 and 106.9 mg/g, respectively. Thermodynamic investigation suggested that the removal of Hg (II) and Cr (VI) by P-NZVI was an endothermic and spontaneous process. The less values of Delta H-0 for Hg (II) than those for Cr (VI) demonstrated that more thermal energy was needed to remove Cr (VI) than Hg (II) at the same reaction rate. |
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Keyword | Nanoscale Zero-valent Iron
Pumice
Mercury (Ii)
Chromium (Vi)
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Subject Area | 环境地球化学
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Indexed By | SCI
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Language | 英语
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Document Type | 期刊论文
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Identifier | http://ir.gyig.ac.cn/handle/352002/5986
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Collection | 环境地球化学国家重点实验室_环境地球化学国家重点实验室_期刊论文
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Recommended Citation GB/T 7714 |
Tingyi Liu,Zhong-Liang Wang,Yanqiu Sun. Manipulating the morphology of nanoscale zero-valent iron on pumice for removal of heavy metals from wastewater[J]. Chemical Engineering Journal,2015,263(1):55-61.
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APA |
Tingyi Liu,Zhong-Liang Wang,&Yanqiu Sun.(2015).Manipulating the morphology of nanoscale zero-valent iron on pumice for removal of heavy metals from wastewater.Chemical Engineering Journal,263(1),55-61.
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MLA |
Tingyi Liu,et al."Manipulating the morphology of nanoscale zero-valent iron on pumice for removal of heavy metals from wastewater".Chemical Engineering Journal 263.1(2015):55-61.
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