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Chemical composition and source apportionment of rainwater at Guiyang, SW China
Xiao Hong-Wei; Xiao Hua-Yun; Long Ai-Min; Wang Yan-Li; Liu Cong-Qiang
2013
Source PublicationJournal of Atmospheric Chemistry
Volume70Issue:3Pages:269-281
AbstractThis study systematically analyzed the concentrations of cations and anions and determined the pH in the rainwater at Guiyang from Oct. 2008 to Sep. 2009. The pH in the rainwater varied between 3.35 and 9.99 with a volume-weighted mean value of 4.23. The volume-weighted mean concentrations of anions followed the order SO4 (2-)> Cl-> F-> NO3 (-), whereas the volume-weighted mean concentrations of cations followed the order Ca2+> NH4 (+)> Na+> Mg2+> K+. This finding indicates that SO4 (2-) was the main anion and that Ca2+ and NH4 (+) were the main cations. Significant correlations between each pair of ions (SO4 (2-), NO3 (-), NH4 (+), Ca2+, and Mg2+) were observed, suggesting that CaSO4, Ca(NO3)(2), MgSO4, Mg(NO3)(2), NH4NO3, (NH4)(2)SO4, and/or NH4HSO4 exist in the atmosphere at Guiyang. The soil-derived species (such as Ca2+) played an important role in the neutralization of the acidity in rainwater. The SO4 (2-) and NO3 (-) in the rainwater were mainly from anthropogenic sources, and their contributions accounted for 98.1 % and 94.7 %, respectively. NH4 (+) was also most likely derived from anthropogenic sources, such as domestic and commercial sewage, and played an important role in the neutralization of the rainwater at Guiyang.
KeywordRainwater Chemical Composition Anthropogenic Source Source Contribution
Subject Area环境地球化学
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.gyig.ac.cn/handle/352002/5003
Collection环境地球化学国家重点实验室_环境地球化学国家重点实验室_期刊论文
Recommended Citation
GB/T 7714
Xiao Hong-Wei,Xiao Hua-Yun,Long Ai-Min,et al. Chemical composition and source apportionment of rainwater at Guiyang, SW China[J]. Journal of Atmospheric Chemistry,2013,70(3):269-281.
APA Xiao Hong-Wei,Xiao Hua-Yun,Long Ai-Min,Wang Yan-Li,&Liu Cong-Qiang.(2013).Chemical composition and source apportionment of rainwater at Guiyang, SW China.Journal of Atmospheric Chemistry,70(3),269-281.
MLA Xiao Hong-Wei,et al."Chemical composition and source apportionment of rainwater at Guiyang, SW China".Journal of Atmospheric Chemistry 70.3(2013):269-281.
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