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湘南瑶岗仙钨矿床成矿流体地球化学
其他题名Geochemistry of the ore-forming fluid of the Yaogangxian tungsten deposit in southern Hunan, China
陈宏伟
2008-05-27
学位授予单位中国科学院地球化学研究所
学位授予地点地球化学研究所
学位名称博士
关键词瑶岗仙钨矿床 成矿流体 氦、氩同位素 碳、氧、硫稳定同位素 矿床成因 华南
摘要瑶岗仙钨矿床位于湘东南后加里东隆起和湘、桂、粤北海西—印支坳陷带的交接部位,是南岭地区最典型的石英脉型钨矿床之一。为了深入研究瑶岗仙钨矿的成矿机制,本文在野外地质工作基础上,选取有代表性的样品,进行了氦、氩同位素以及碳、氧、硫稳定同位素研究,探讨了矿床成矿流体的来源,成岩成矿的关系,并初步讨论了矿床的成因模式。论文主要获得以下认识: (1)对瑶岗仙矿区不同硫化物中流体包裹体的氦、氩同位素系统测定表明,该矿床毒砂流体包裹体中3He/4He比值为0.58~2.60 Ra;黄铁矿和黄铜矿流体包裹体中3He/4He比值分别为0.41~1.26 Ra 和0.37~0.43 Ra,黑钨矿流体包裹体中氦同位素组成相对变化较大,其3He/4He比值为0.05~0.49 Ra,这些He同位素组成均明显高于地壳相应值;毒砂流体包裹体中的40Ar/36Ar变化范围在309.94~454.39;黄铁矿流体包裹体中的40Ar/36Ar变化范围在409.12~1822.31;黄铜矿和黑钨矿流体包裹体中的40Ar/36Ar变化范围分别为673~886和325~903,明显高于饱和大气雨水的40Ar/36Ar值。上述氦、氩同位素组成揭示瑶岗仙钨矿床中的成矿流体具有壳、幔两端元混合的特点。结合区域地质构造演化和成矿年代学的研究成果,本文认为瑶岗仙钨矿床的成矿流体是瑶岗仙花岗岩浆分异出的含有地幔He的岩浆流体与大气成因地下水二端元混合的产物。 (2)层解石和方解石的C、O同位素显示,该矿方解石的13CPDB和18OSMOW的变化范围为-2.2‰~ -7.0‰(均值为-4.8‰)和5.6‰~14.4‰(均值为11.3‰);层解石的13CPDB和18OSMOW的变化范围为-5.5‰~ -6.3‰(均值为-5.8‰)和12.7‰~14.3‰(均值为13.8‰);该矿方解石、层解石的C、O同位素组成与赣南西华山钨矿床非常类似。这些C、O同位素指示,该矿的成矿流体主要来自岩浆水,后期有少量大气降水的参与。 (3)对瑶岗仙矿区不同硫化物的硫同位素研究表明,该矿硫化物δ34S值的变化范围很窄,为-2.0‰~1.5‰之间,且具有明显的塔式分布。这些特征暗示,该矿的硫来源单一,主要来自岩浆。 (4)瑶岗仙花岗岩过去被视为典型的S型花岗岩,但本文研究发现该花岗岩普遍含有地幔He。结合区域构造背景的最新研究成果,本文认为,原来被认为“由地壳物质重熔形成的”瑶岗仙S型花岗岩体,实际上也是一种岩石圈伸展背景条件下壳幔相互作用的产物,地幔物质和能量的参与在该花岗岩的形成过程中发挥了重要作用。 (5)瑶岗仙钨矿床与矿区复式花岗岩体具有密切时空关系,而且该矿的主要成矿流体和成矿物质均来自矿区花岗岩,故两者亦应具成因联系。
其他摘要The Yaogangxian tungsten deposit, tectonically located in the intersection part of the post-Caledonian uplift and the Hercynian-Indosinian depress belt, is a typical quart-vein tungsten deposit in the Nanling region, South China. On the base of detailed field investigation, a systematic study on helium and argon isotope and carbon, oxygen and sulfur stable isotope has been carried out, and the sources of ore-forming fluid and the relationship between granite intrusion and tungsten mineralization are discussed. Finally, a possible genetic model is proposed. The main conclusions are listed as follows: (1) The helium and argon isotopic compositions of fluid inclusions in different sulfides collected from the Yaogangxian deposit have been analyzed. It is shown that, 3He/4He ratios of fluid inclusions in arsenopyrite are 0.58~2.60 Ra, 0.41~1.26 Ra in pyrite, 0.37~0.43 Ra and 0.05~0.49 Ra in chalcopyrite and wolframite, respectively, obviously higher than that of the crust. 40Ar/36Ar ratios of fluid inclusions in arsenopyrite are 309.94~454.39, 409.12~1822.31 in pyrite, 672.87~885.67 and 324.81~903.09 in chalcopyrite and wolframite, respectively, which are obviously higher than that of air-saturated meteoric water. The above helium and argon isotope values indicate that the ore-forming fluid in this deposit is a mixture between mantle- and crustal-derived fluids. Combined with the regional tectonic evolution and geochronological data, it is concluded that the ore-forming fluid in this deposit is a mixture of mantle fluid and crustal fluids; the former is of magmatic origin, differentiated from the Yaogangxian granite and enriched in mantle-source helium, the latter is of meteoric origin. (2) Carbon and oxygen isotopic compositions of calcite and argentine indicated that, the 13CPDB values of calcite range from -2.2‰ to -7.0‰ (averaging -4.8‰) and the 18OSMOW values of calcite vary between 5.6‰ and 14.4‰ (averaging 11.3‰); the 13CPDB values of argentine range from -2.2‰ to -7.0‰ (averaging -5.8‰) and the 18OSMOW values of argentine range from 5.6‰ to 14.4‰ (with an average of 13.8‰). The above carbon and oxygen isotope data coincides well with those of calcite and argentine in the Xihuashan deposit, southern Jinagxi. The result show that the ore-forming fluid is mainly derived form the magma, and meteoric water take part in the tungsten mineralization at the late mineralization stage. (3) The δ34S values of different sulfides collected from the Yaogangxian mining district show a relatively narrow range, varying from -2.0‰ to -1.5‰, and display obvious tower distribution. It is suggested that the sulfur mainly comes from magma. (4) The Yaogangxian granite was considered as one of typical S-type granite, but it is revealed in this dissertation that the granite usually contains mantle-origin helium. Combined with the regional tectonic setting, we can confirm that this so-called S-type granite actually resulted from the geologic setting of lithospheric extension and crust-mantle interaction, mantle-source substance and energy play an important role during granite intrusion. (5)The Yaogangxian tungsten deposit has a close temporal, spatial and genetic relationship with the granite complex in the mining district. Moreover, the granite has predominately provided the ore-forming fluid and metallogenic materials for tungsten mineralization, thus both are genetically associated.
页数53
语种中文
文献类型学位论文
条目标识符http://ir.gyig.ac.cn/handle/352002/3426
专题研究生_研究生_学位论文
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陈宏伟. 湘南瑶岗仙钨矿床成矿流体地球化学[D]. 地球化学研究所. 中国科学院地球化学研究所,2008.
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